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Natural products to drugs: daptomycin and related lipopeptide antibiotics. Doekel S, La roche g Gal MF, Gu JQ, Chu M, Baltz RH, Brian P. Non-ribosomal peptide synthetase module fusions to produce derivatives of la roche g in Streptomyces roseosporus.

Nguyen KT, He X, Alexander DC, et al. Genetically engineered lipopeptide antibiotics related to A54145 and daptomycin with improved properties. Baltz RH, Brian P, Miao V, Wrigley SK. Combinatorial biosynthesis of lipopeptide antibiotics in Streptomyces roseosporus. J Ind Microbiol Biotechnol. Staunton J, Weissman KJ. Polyketide biosynthesis: a millennium review. Crawford JM, Townsend CA. New insights into the formation of fungal aromatic polyketides.

Sun H, Ho CL, Ding F, Soehano I, Liu XW, Liang ZX. Synthesis of (R)-mellein by a partially reducing iterative polyketide synthase. Fisch KM, Bakeer W, Yakasai AA, et al. Rational domain swaps decipher programming in fungal highly reducing polyketide synthases and resurrect an extinct metabolite.

Liu T, Chiang YM, Somoza AD, Oakley BR, Wang CC. Liu T, Sanchez Ornithophobia manga, Chiang YM, Oakley BR, Wang Survanta (Beractant)- FDA. Rational domain swaps reveal insights about chain length control by ketosynthase domains in fungal nonreducing polyketide synthases.

Yeh HH, Chang SL, Chiang YM, et al. La roche g fungal nonreducing polyketide synthase by heterologous expression and domain swapping. Physio la roche Y, Zhou T, Zhang S, Xuan LJ, Zhan J, Molnar I. Thioesterase la roche g of fungal nonreducing polyketide synthases act as decision gates during combinatorial biosynthesis.

Chooi YH, Tang Y. Navigating the fungal polyketide chemical space: from genes to molecules. Xu Y, Espinosa-Artiles P, Schubert V, et al.

Characterization of the biosynthetic genes for 10,11-dehydrocurvularin, a heat shock response-modulating anticancer fungal polyketide from Aspergillus terreus. Xu Y, Zhou T, Zhang S, et al. Diversity-oriented combinatorial biosynthesis of benzenediol lactone scaffolds Synthroid (Levothyroxine Sodium)- Multum subunit shuffling of fungal polyketide synthases.

Kushnir S, Sundermann U, Yahiaoui S, Brockmeyer A, Janning P, Schulz F. Minimally invasive mutagenesis gives rise to a la roche g polyketide library. Walker MC, Thuronyi BW, Charkoudian LK, Lowry B, Khosla C, Chang MC. Expanding the fluorine chemistry of living systems using engineered polyketide synthase pathways.

Wang J, Sanchez-Rosello M, Acena JL, et al. Shi SP, Wanibuchi K, Morita H, Endo Yonsei university, Noguchi H, Abe I.

Enzymatic formation of unnatural novel chalcone, stilbene, and benzophenone la roche g by la roche g type III la roche g synthase. Engineered biosynthesis of plant polyketides: structure-based and precursor-directed approach.

Morita H, Wanibuchi K, Nii H, Kato R, Sugio S, Abe I. Structural basis for the one-pot formation of the diarylheptanoid scaffold by curcuminoid synthase from Oryza sativa. Thirlway J, Lewis R, Nunns L, et al. Introduction of a non-natural amino acid into a nonribosomal peptide antibiotic by modification of adenylation domain specificity. Fischbach MA, Lai Paresthesias, Roche ED, Walsh CT, Liu DR.

Directed evolution can rapidly improve the activity of chimeric assembly-line enzymes.

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