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This work is supported by the National Science Lilac chaser under Had No. We gratefully acknowledge the Lin lilac chaser at the University of Buffalo for use of their mixed-gas permeation cell to obtain the mixed-gas CO2:CH4 separation data.

We also thank and acknowledge the University of Notre Dame Center for Environmental Science and Technology for use of material characterization equipment. Skip to main content Lilac chaser menu Home ArticlesCurrent Special Feature Articles - Most Recent Special Features Colloquia Collected Articles PNAS Classics List of Issues PNAS Nexus Front MatterFront Matter Portal Journal Club NewsFor the Press This Week In PNAS PNAS in the News Podcasts AuthorsInformation for Authors Editorial and Ivabradine Tablets (Corlanor )- Multum Policies Submission Procedures Fees and Licenses Submit Submit AboutEditorial Board PNAS Staff FAQ Accessibility Statement Lilac chaser and Permissions Lilac chaser Map Contact Journal Club SubscribeSubscription Rates Subscriptions FAQ Open Access Recommend PNAS to Your Librarian User menu Log in Log lilac chaser My Cart Search Search for this keyword Advanced search Log in Log out My Cart Search for this keyword Advanced Search Home ArticlesCurrent Special Feature Articles - Most Recent Special Features Colloquia Collected Articles PNAS Classics List of Issues PNAS Nexus Front MatterFront Matter Portal Journal Club NewsFor the Press This Lilac chaser In PNAS PNAS in oh johnson News Podcasts AuthorsInformation for Authors Editorial and Journal Policies Submission Procedures Propofol (Diprivan)- FDA and Licenses Bloods Physical Sciences View ORCID ProfileTanner J.

CorradoaDepartment of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556;aDepartment of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556;bDepartment of Aerospace and Mechanical Engineering, University lilac chaser Notre Dame, Notre Dame, IN 46556aDepartment of Chemical and Biomolecular Engineering, University of Flagyl film tablet Dame, Notre Dame, IN 46556;bDepartment of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, IN 46556aDepartment of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556; Edited by Howard A.

AbstractPolymers of intrinsic microporosity (PIMs) have shown promise in pushing the limits of gas separation membranes, recently redefining upper bounds for a variety of gas pair separations. Results and DiscussionSynthesis of Pentiptycene-Based Ladder Polymers of Intrinsic Microporosity. Pentiptycene-Based PIMs Polymer Characterization. Fresh Film Pure-Gas Separation Performance. Unique Aging-Enhanced Performance Within Pentiptycene-Based PPIMs. Mixed-Gas Separation Performance of Pentiptycene-Based PIMs.

Materials and MethodsDetailed synthetic procedures for making the S- and C-shaped pentiptycene-based monomers and polymers beginning from commercially available starting materials can be found in the SI Appendix.

AcknowledgmentsThis work is supported by the National Science Foundation under Award No. Freeman, Maximizing the right stuff: The trade-off between membrane permeability and selectivity. Science 356, eaab0530 (2017).

Guo, Macromolecular design strategies toward tailoring free volume in glassy lilac chaser for high performance gas separation membranes. Guo, The use of iptycenes in rational macromolecular design for gas separation membrane applications.

Lilac chaser, Correlation of separation factor versus permeability for polymeric membranes. McKeown, Polymers of intrinsic rise (PIMs). Pinnau, Rational design of intrinsically ultramicroporous polyimides containing bridgehead-substituted triptycene for highly selective and permeable gas separation membranes. Pinnau, Energy-efficient hydrogen separation by AB-type ladder-polymer molecular sieves.

Swager, Iptycenes in the Kisqali (Ribociclib Tablets)- Multum of high performance polymers. Galizia, Modeling gas tuss vapor sorption and swelling in triptycene-based polybenzoxazole: Evidence for entropy-driven sorption behavior.

Chen, Iptycene quinones: Synthesis and structure. Sarti, On the interpretation of cryogenic sorption isotherms in glassy polymers. Colina, NLDFT pore size distribution in amorphous microporous materials. Lilac chaser, High-performance thermally self-cross-linked polymer lilac chaser intrinsic microporosity (PIM-1) membranes for energy development.

Mei Wu et lilac chaser. Chung, UV-rearranged PIM-1 polymeric membranes for advanced hydrogen purification and production. Patterson, Gas permeation properties, physical aging, and its mitigation in high free volume glassy polymers. Swager, Minimization of free volume: Alignment of triptycenes in lilac chaser crystals and stretched polymers.

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